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Vanadyl acetylacetonate 3153-26-2

Acetylacetone oxyvanadium [VO(acac)2] is a common oxidation catalyst, which combines with tert-butyl hydrogen peroxide (TBHP) and other oxidants to rapidly oxidize into homogeneous 5-valent vanadium compounds under the reaction system, which can effectively oxidize a variety of organic functional groups, such as tertiary amine oxidation to N-oxide, sulfide oxidation to sulfoxide, epoxidation of olefins and other reactions, especially can carry out regional and chiral oxidation.
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Vanadyl acetylacetonate Basic information
Reaction
Product Name: Vanadyl acetylacetonate
CAS: 3153-26-2
MF: C10H14O5V
MW: 265.16
EINECS: 221-590-8
Mol File: 3153-26-2.mol
Vanadyl acetylacetonate Chemical Properties
Melting point 235 °C (dec.)(lit.)
Boiling point 140°C 13mm
bulk density 450kg/m3
density 1,4 g/cm3
vapor pressure 0Pa at 20℃
Fp 79 °C
storage temp. Store below +30°C.
solubility Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene
form Crystalline Powder
Specific Gravity 1.4
color Green to blue-green
Water Solubility practically insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 4138236
Exposure limits NIOSH: Ceiling 0.05 mg/m3
Stability: Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.
InChIKey JFHJZWAQYMGNBE-SUKNRPLKSA-L
LogP 0.4 at 20℃
CAS DataBase Reference 3153-26-2(CAS DataBase Reference)
NIST Chemistry Reference Bis(2,4-pentanedionato)oxovanadium(iv)(3153-26-2)
EPA Substance Registry System Vanadium, oxobis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-5-21)- (3153-26-2)

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