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Disodium Octaborate Tetrahydrate: Uses, Properties & Applications

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Disodium octaborate tetrahydrate is a versatile inorganic borate compound with a wide variety of applications including wood preservation, agricultural micronutrient fertilizers, flame-retardant formulations, construction materials, and a variety of industrial chemical applications. It is a key raw material for manufacturers seeking reliable boron-based solutions, due to its high boron content, water solubility and multi-functionality.

In view of the increasing interest in effective protection of wood, concentrated boron fertilizers and functional additives, disodium octaborate tetrahydrate remains of interest for chemical manufacturers, agricultural suppliers, construction companies and industrial formulators.

What Is Disodium Octaborate Tetrahydrate?

Disodium octaborate tetrahydrate is an inorganic borate salt containing sodium, boron, oxygen, and water of crystallization. It is commonly abbreviated as DOT and is also known as sodium octaborate tetrahydrate.

The compound is generally supplied as a white crystalline powder or granular solid. Because it provides a concentrated source of water-soluble boron, it is used in agricultural formulations and industrial applications, particularly wood preservatives and certain flame-retardant systems.

Disodium octaborate tetrahydrate has the CAS number 12280-03-4. Its chemical formula is commonly written as Na₂B₈O₁₃·4H₂O.

Basic Chemical Information

Property

Description

Product name

Disodium Octaborate Tetrahydrate

Abbreviation

DOT

CAS number

12280-03-4

Molecular formula

Na₂B₈O₁₃·4H₂O

Molecular weight

Approximately 412.52 g/mol

Appearance

White powder or crystalline solid

Chemical category

Inorganic borate salt

Main functional component

Boron

Water solubility

Soluble in water; exact solubility depends on temperature and grade

Main applications

Wood preservation, boron fertilizers, flame-retardant formulations, industrial additives


Chemical and Physical Properties of Disodium Octaborate Tetrahydrate

Understanding the properties of disodium octaborate tetrahydrate helps manufacturers determine whether it is suitable for a particular formulation or production process.

1. Rich in Boron

A major advantage of disodium octaborate tetrahydrate is the concentration of boron content. The commercial fertilizer and industrial grade specifications generally list elemental boron content between 20-21%. However, the actual value is dependent on the product composition and specification.

Boron is a necessary micronutrient for plant growth. The chemistry of borates is also important in some industrial uses of wood preservatives and flame-retardant systems.

2.Water Solubility

Disodium octaborate tetrahydrate dissolves in water, making it useful for preparing aqueous solutions and formulated products.

It is especially important for its solubility in:

Water Soluble Fertilizers of Boron

Foliage Nutrient Formulations

Fertigation products

WOOD PRESERVATIVE TREATMENT SOLUTIONS

Some water-based industrial preparations

The actual performance of dissolution depends upon temperature, water quality, concentration, particle characteristics and other ingredients.

3. White Powder Appearance

Commercial disodium octaborate tetrahydrate is generally available as a white powder or granular material. The appearance and particle properties are consistent so manufacturers can rely on the mixing, handling and dissolution performance.

4. Borate-Based Functional Properties

The compound is useful in those areas where borate chemistry provides a useful function. Depending on the formulation, this may be biological protection of wood, boron nutrition of crops or flame retardant performance of compatible materials.

Note that disodium octaborate tetrahydrate does not perform the same in every application. The outcome depends on the concentration, method of application, substrate and formulation design.

What Is Disodium Octaborate Tetrahydrate Used For?

Main applications of disodium octaborate tetrahydrate:

Wood Preservation and Protection Against Wood Destroying Organisms.

Micronutrient fertilizers for agriculture.

Flame-retardant treatments for compatible materials.

Construction materials and cellulose insulation.

Paints, coatings, adhesives, and selected industrial formulations.

Specialized chemical products requiring a soluble boron source.

These applications are documented in chemical safety and regulatory references, including the European Chemicals Agency-related background information on disodium octaborate and Canadian government guidance on borate wood preservatives.

Application in Wood Preservation

Wood preservation is one of the most established applications of disodium octaborate tetrahydrate.

Wood can be damaged by decay fungi, termites, and other wood-boring insects. Borate-based preservatives are used to help protect susceptible wood products when the treatment is appropriate for the intended service environment.

Disodium octaborate tetrahydrate is water-soluble, allowing it to be incorporated into treatment solutions that penetrate wood under suitable processing conditions.

1.Typical Wood Preservation Applications

Disodium octaborate tetrahydrate may be used in preservative formulations for:

Structural timber

Interior framing lumber

Wooden building components

Furniture and joinery materials

Wood-based composite products

Selected wood-foam composite structural components

The exact applications permitted depend on the product registration, treatment process, wood species, target organism, and local regulations.

2.How Does It Protect Wood?

If the borate treatment is correct, the borate active ingredient is taken up by the wood. Under proper conditions it can assist in protecting treated material against susceptible fungi and insects destructive to wood.

Industrial treatment may involve diffusion, surface application, or pressure impregnation, depending on the wood product and the preservative system.

A typical industrial process includes:

Preparation of a borate treatment solution.

Loading and conditioning of the wood.

Application of the treatment using an approved process.

Control of chemical uptake and retention.

Drying or conditioning, where required.

Quality inspection and documentation.

The treatment must achieve the retention and penetration requirements established for the intended use.

3.Important Limitation: Exposure to Moisture

Borates are water soluble. Wood treated with borates can lose the preservative if exposed to free water for long periods of time or leached repeatedly.

The Canadian government states that borate-treated wood is generally suitable for applications that are protected from continuous free-water exposure and that are not in contact with the ground.

Therefore, the choice of preservative and treatment process is critical to long term performance.

Application in Agricultural Micronutrient Fertilizers

Another important application of disodium octaborate tetrahydrate is the production of boron-containing fertilizers.

Boron is needed by plants in small amounts for normal growth. It is involved in cell wall formation, reproductive development, pollen function, and other physiological processes.

Adverse effects on flowering, fruit development, growing points and crop quality can result from deficiency of boron. When properly formulated in fertilizer mixes, disodium octaborate tetrahydrate can serve as a concentrated source of soluble boron.

1.Agricultural uses

Possible applications are:

Boron water-soluble fertilizers

Liquid micronutrients concentrated

Foliar nutrient contents.

Fertigation products”

Boron enriched compound fertilizers

Multi-micronutrient fertilizer blends

Specialty Nutrients for Horticulture and Field Crops

Disodium octaborate tetrahydrate can be included in fertilizer products to deliver boron to plants through soil application, foliar application or irrigation, if the product label and formulation are appropriate for the intended mode of delivery.

2. Example: Formula of Boron Fertilizer

A fertilizer manufacturer can include disodium octaborate tetrahydrate as a source of boron in a water soluble micronutrient mixture.

A typical development process involves:

Defining the target elemental boron concentration.

Selecting a suitable grade of disodium octaborate tetrahydrate.

Evaluating dissolution in the intended water system.

Checking compatibility with other nutrients and additives.

Testing solution stability and storage performance.

Establishing application directions and quality-control specifications.

Boron has a relatively narrow range between deficiency and excess for many crops. Fertilizer dosage should therefore be based on crop requirements, soil or tissue testing, irrigation-water quality, and local agronomic recommendations.

Application as a Flame-Retardant Component

Disodium octaborate tetrahydrate is also used in certain flame-retardant formulations.

The contribution of borate compounds to improvements of fire performance can be achieved by mechanisms which may involve thermal decomposition, formation of protective residues and changes in the behavior of combustible materials. It is contingent upon the material and the formula how does it work and how well.

1.Common Application Areas

Potential uses include treatments for:

Cellulose insulation

Paper and paper-based products

Selected textile materials

Wood-based composites

Certain construction materials

Compatible industrial formulations

In cellulose-based materials, borate additives may be used to help reduce flammability and support the required fire-performance characteristics.

2.Why Is Formulation Important?

Disodium octaborate tetrahydrate should not be assumed to make a material fireproof when used alone.

Flame-retardant performance depends on factors such as:

Borate concentration and distribution

Substrate composition

Treatment method

Moisture exposure

Thermal conditions

Applicable fire-testing standards

Manufacturers should test the finished material against the relevant fire-performance requirements rather than relying solely on the presence of a borate ingredient.

Applications in Construction Materials and Cellulose Insulation

The construction industry uses borate compounds in selected building-material formulations.

Disodium octaborate tetrahydrate may be incorporated into systems involving cellulose insulation, wood-based construction products, and other compatible materials.

Potential functions include contributing to biological protection and supporting fire-performance objectives, depending on the specific formulation and regulatory approval.

Standard Applications

Cellulose Insulations

Construction composites selected

Wooden building elements

Special formulations of building material

Some industrial insulation materials

For insulation producers, important criteria for evaluation include the distribution of the additive, moisture sensitivity, compatibility with the production process and performance in relevant fire and bio-resistance tests.

Applications in Paints, Coatings and Adhesives

Disodium octaborate and related borate materials are also registered or reported for certain industrial applications, including paints, coatings, adhesives and construction products.

In these formulations the material may be used as a functional (boron-containing) ingredient rather than as a primary film forming component.

Its adequacy depends on:

Compatibility with binder system

Water content and pH

Solubility and dispersion demands

Interaction with other additives

Storage stability

Final coating or adhesive performance

The entire system should be tested by formulators to find a suitable grade.

Frequently Asked Questions About Disodium Octaborate Tetrahydrate

What is disodium octaborate tetrahydrate mainly used for?

It is mainly used in wood preservation, boron micronutrient fertilizers, some flame retardant systems, construction materials and certain industrial formulations.

Is disodium octaborate tetrahydrate used as a fertilizer?

“Yeah. Boron source in selected fertilizer products, including water soluble micronutrient formulations. Excess boron can damage crops, so application rates must follow product label and agronomic recommendations.

Can disodium octaborate tetrahydrate protect wood?

It can be used in registered borate-based wood-preservative products to protect suitable wood materials against susceptible fungi and wood-destroying insects. Performance depends on treatment conditions and the service environment.

Is disodium octaborate tetrahydrate a flame retardant?

It may be used as an ingredient in some flame retardant treatments and formulations. The final material shall be tested for compliance with the applicable fire-performance requirements.

What is the difference between disodium octaborate tetrahydrate and borax?

Both are sodium borate compounds , but have different chemical compositions , hydration states and boron contents . Disodium octaborate tetrahydrate is often selected where a concentrated, soluble source of boron is needed. They should not be interchanged without checking formulation requirements.


Disodium octaborate tetrahydrate is a significant inorganic borate compound that finds use in wood preservation, agriculture, flame retardant formulations, construction materials, and in certain industrial chemical systems.


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