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Glycerol formal CAS 4740-78-7

Glycerol acetal (GF) is a light glycerol acetal, composed of approximately 60% 5-hydroxy-1, 3-dioxane and approximately 40% 4-hydroxymethyl-1, 3-dioxane. In the presence of an acidic catalyst, glycerol reacts with formaldehyde to form acetone. The potential of GF as an injection solvent for toxicity tests has been reported.
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  • 4740-78-7

Glycerol formal Basic information
Product Name: Glycerol formal
CAS: 4740-78-7
MF: C4H8O3
MW: 104.1
EINECS: 225-248-9
Mol File: 4740-78-7.mol
Glycerol formal Chemical Properties
Boiling point 192-193 °C(lit.)
density 1.203 g/mL at 25 °C(lit.)
refractive index n20/D 1.451(lit.)
Fp 97°C
storage temp. Inert atmosphere,2-8°C
solubility Miscible with water and with ethanol (96 per cent).
pka 13.68±0.20(Predicted)
form clear liquid
color Colorless to Almost colorless
InChIKey VCKSNYNNVSOWEE-UHFFFAOYSA-N
CAS DataBase Reference 4740-78-7(CAS DataBase Reference)
NIST Chemistry Reference 1,3-Dioxan-5-ol(4740-78-7)

Items

Specifications

Results

Appearance

Clear, colourless liquid

Complies

Solubility

Miscible with water and with ethanol (96 per cent)

Complies

Purity

≥99%

99.1%

Identification



A) Relative

density

See test

Complies

B) Refractive index

See test

Complies

C) IR

Comparison glycerol formal CRS

Complies

Test


pH

4.0 to 6.5

6.0

Relative density

1.210 to 1.220

1.214

Refractive index

1.445 to 1.455

1.449

Peroxide (H2O2)

≤ 0.0015

Complies

Heavy metals

≤0.001

0.0014

Water

≤ 0.5%

0.12

Formaldehyde content

≤0.02%

0.002

Stograge

Under nitrogen, in an airtight container.


Conclusion:The product conforms to BP2013

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