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50-21-5
futurechemical
50-21-5
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Chinese name | Lactic acid/2-hydroxypropionic acid |
English name | Lactic acid / 2-Hydroxypropanoic acid |
Molecular formula | C₃H₆O₃ |
molecular weight | 90.08 |
CAS number | 50-21-5 (DL-lactic acid), 79-33-4 (L-lactic acid) |
Appearance | Colorless to slightly yellow transparent viscous liquid (commercially available solutions are mostly 80%~90% aqueous solutions). |
Sourness characteristics | Soft, rounded, with a slightly milky finish—a stark contrast to the sharpness of citric acid. |
pH | Strongly acidic (pKa = 3.86, pH of 1% solution ≈ 2.4) |
Lactic acid has two "origins" that make it unique among food acids:
1. It is a naturally occurring component in fermented foods—yogurt, sauerkraut, kimchi, sourdough bread, soy sauce, cheese… In these traditional fermented foods with a history of thousands of years, lactic acid is a natural byproduct produced by lactic acid bacteria after metabolizing sugars. In these foods, it is not “added” but is already present.
2. It is a metabolic byproduct of the body itself—the soreness in your muscles after exercise is chemically caused by lactic acid. Your body recognizes it, knows how to metabolize it, and does not reject it.
These two identities give lactic acid a "natural sense of trust" in consumers' minds that cannot be replicated by chemically synthesized acids (such as phosphoric acid and fumaric acid).
Lactic acid is one of the most commonly used organic acidity regulators in the food industry. Its acidity profile differs fundamentally from that of citric acid.
contrast | Citric acid (E330) | Lactic acid (E270) |
sourness | Sharp, stimulating, and explosive | Soft, smooth, and with a clean aftertaste |
Compatibility with fermented foods | "Added" acid | Naturally present in fermented foods |
Applicable Scenarios | Soft drinks and candies with a strong sour taste are needed. | Dairy products, beer, and meat products that require a mild sour taste |
Lactic acid is widely used as an acidity regulator:
Food categories | effect | The uniqueness of lactic acid |
dairy products | Natural acid – lactic acid is naturally present in yogurt. | It will not introduce the feeling of "added acid". |
Soft drinks and juice | The fruit acidity is mild—unlike citric acid, it doesn't mask the natural aroma of the fruit. | The acidity is less noticeable, making the fruit flavor more prominent. |
Beer (brewing process) | pH adjustment during the saccharification stage is the source of acidity in sour beer. | More natural than phosphoric acid (an inorganic acid) – a preference of craft breweries |
Sauces and salad dressings | Mild acidity + antiseptic buffer | The acidity has rich layers. |
Vinegar and vinegar drinks | When combined with acetic acid, it creates a complex sour taste. | Unlike acetic acid, which is a single irritant. |
Lactic acid is the most "natural" food preservation strategy—it doesn't involve adding "chemical poison" to food, but rather creating an acidic environment that bacteria dislike.
Protected food | lactic acid as a preservative | Mainly targeted microorganisms |
Ready-to-eat meat products | Spray or soak the surface with diluted lactic acid solution | Listeria monocytogenes – the most dangerous pathogenic bacterium to refrigerated ready-to-eat meat products. |
Freshly cut vegetable salad | Pre-packaging soaking in lactic acid solution | Salmonella, Escherichia coli O157:H7 |
Seafood and fish | Surface treatment | Spoilage bacteria – prolonging freshness in the freezer |
Pickled vegetables | Lactic acid is used to adjust the initial pH of the brine, accelerating natural fermentation. | Putrefactive bacteria provide a "first-mover advantage" for lactic acid bacteria. |
The advantages of lactic acid preservatives are:
● Colorless – will not discolor the surface of the meat;
● Tasteless (at low concentrations) – the treatment does not affect the natural flavor of the food;
● It is not considered a "chemical preservative" - in the food regulations of many countries, lactic acid, as an acidity regulator, does not need to be separately labeled as a "preservative" like sodium benzoate or potassium sorbate;
● The USDA permits the use of lactic acid as an antimicrobial intervention in organic meat processing.
The flavor of some foods is not defined by sugar or salt, but by acid. The application of lactic acid as a flavoring agent:
Sour candies and chewing gum: a mild sour taste—not harsh on the tongue and leaves no bitter aftertaste;
Acidic gelling candies (such as the filling of candied hawthorn): Lactic acid is pH compatible with pectin gel—citric acid may cause pectin to coagulate prematurely;
Children's food: For children's taste buds, the mild acidity of lactic acid is more palatable than the sharp acidity of citric acid.
In beer brewing, lactic acid is used throughout the entire process from raw materials to finished product:
Saccharification stage: The pH of the wort is adjusted from its natural value of 5.6. Adjusted from 5.8 to 5.2 5.4 – This is the optimal activity range for α-amylase and β-amylase.
Fermentation stage: Some beer styles (sour beer, Gose, Berliner Weisse) require an acidic environment during fermentation;
Finished product conditioning: Fine-tuning the pH before beer filtration and bottling—improving the beer's biological stability (bacteria are less likely to grow at low pH) and refreshing taste.
The use of lactic acid in baking is often unnoticed by consumers, but it is a common ingredient in industrial bread recipes:
Delaying bread staling: An acidic environment alters the gelatinization and retrogradation behavior of starch—resulting in a softer bread crust that stays soft for a longer time;
Enhancing gluten strength: Slightly acidic (pH 5.0~5.5) is the optimal pH range for gluten formation—after adjusting the acidity with lactic acid, the dough has better workability and the bread has a larger volume;
Natural preservatives: The acidic microenvironment on the surface of bread inhibits mold growth—extending the number of days it doesn't mold.
Flavor enhancement in sourdough: Lactic acid in sourdough is a natural byproduct of the fermentation process.
In the dairy industry, lactic acid has a dual role—it is both an acid naturally produced by fermenting bacteria and a food additive that can be added during processing.
Yogurt and fermented milk beverages: Replenishing the acidity lost due to insufficient fermentation—ensuring consistent product taste;
Mozzarella cheese: In the hot stretching process, lactic acid adjusts the pH of the curd, allowing casein to be stretched into long strands when heated—one of the chemical prerequisites for the cheese strands you pull when eating pizza is that the pH is just right.
Cheese curd: Lactic acid promotes the action of rennet—accelerating curd formation;
Butter and cream: used as a source of acidity in some fermented creams.
Lactic acid is used in every stage of the meat processing industry, from slaughter to packaging:
Carcass spraying: Spraying the surface of cattle or pig carcasses with a 2% to 5% lactic acid solution on the slaughter line—this is a USDA-approved standard intervention to reduce E. coli O157:H7 and Salmonella contamination;
Surface treatment during processing: Ham and bacon are soaked in lactic acid solution before smoking or cooking to reduce the initial bacterial count;
Final product preservation: cooked meat products and sausages—lactic acid and sodium lactate work together to form a key acidic barrier in the "barrier preservation" system—the growth of Listeria monocytogenes is significantly inhibited in an environment with pH < 4.4.
Lactic acid (E270) is the most "natural" of all food acids—it is not a product from a chemical reactor, but rather the metabolic waste excreted by lactic acid bacteria after consuming sugar in a fermentation tank.
It is precisely this origin that gives it a unique character among food products:
Scene | What is lactic acid doing? |
yogurt | It's not an additive—it's an inherent part of yogurt. |
Craft sour beer | It brings a refreshing tartness like green apples—unlike vinegar, unlike lemon. |
Sliced bread | It keeps the bread crust soft for days—while preventing mold from settling in. |
Korean kimchi | It's the weapon of lactic acid bacteria—using acid to kill spoilage bacteria and retain a crisp and tender texture. |
Ready-to-eat ham | When sprayed on a surface, it forms an invisible "acid wall"—Listeria bacteria die upon contact. |
Pizza cheese pull | It adjusts the pH in the mozzarella curd to just right—that's where the stringy texture begins. |
Lactic acid is present in every bite of fermented food you eat, in every package of chilled ready-to-eat meat you buy, and in every craft sour beer you drink—it's there as it always should be. It's not an outsider; it's the language of food itself.